British TV presenter Jameela Jamil, 32, also looked stunning in a rose pink strapless structured gown by Monique Huillier, for her first ever Golden Globe awards.
The Londoner shot to same as a presenter on T4 in 2009 and has since made a name for herself as an actress in The Good Place. Bohemian Rhapsody actress Lucy Boynton, 24, who this week confirmed her relationship with co-star Rami Malek, literally sparkled in a glittery gold number.
Before the show, she gushed: "Off to my first Golden Globes! The custom-made Celine gown was clinched at the waist and long sleeved with a leg slit.
It was a fitting choice, given the 34-year-old actress has a nomination for Best Supporting Actress - after playing Neil Armstrong's wife in First Man.
Meanwhile, Marvellous Mrs Maisel actress Rachel Brosnahan looked sensational in a vibrant yellow gown as she arrived at the awards ceremony.
Rosamund Pike, 39, was also looking glam in a stappy black dress with a casually worn silver jacket.
The Gone Girl actress is nominated for Best Actress in a Motion Picture.
The 32-year-old reality star was papped getting ready and showed off the frock's open back as she went through a few last-minute adjustments.
The Golden Globes is the first big awards ceremony in the Hollywood calendar.
Amy Adams, 44, meanwhile, also opted for bright colours in a blue full-length number.
She has two Golden Globe nominations this year - Best Supporting Actress and Best Actress in a Mini-Series or TV Motion Picture.
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While Sandra, who's hosting this year's event and played MI5 spy Eve, wowed in a white full-length winged gown by Versace and statement earrings.